Characterisation of the aminoxyl (>N–O.) radical BTNO, generated from 1-hydroxybenzotriazole (HBT) by the one-electron oxidant CAN (a CeIV salt), confirms BTNO as the reactive intermediate in oxidations run with the laccase/HBT system.
Spectrophotometric, EPR and kinetic characterisation of the > N-O center dot radical from 1-hydroxybenzotriazole, a key reactive species in mediated enzymatic oxidations / Galli, Carlo; Gentili, Patrizia; Lanzalunga, Osvaldo; M., Lucarini; G. F., Pedulli. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - (2004), pp. 2356-2357. [10.1039/b407835g]
Spectrophotometric, EPR and kinetic characterisation of the > N-O center dot radical from 1-hydroxybenzotriazole, a key reactive species in mediated enzymatic oxidations
GALLI, Carlo;GENTILI, Patrizia;LANZALUNGA, Osvaldo;
2004
Abstract
Characterisation of the aminoxyl (>N–O.) radical BTNO, generated from 1-hydroxybenzotriazole (HBT) by the one-electron oxidant CAN (a CeIV salt), confirms BTNO as the reactive intermediate in oxidations run with the laccase/HBT system.File allegati a questo prodotto
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