The intramolecular aldol condensation of 3-oxocyclohexaneacetaldehydes leading to C(6) epimeric mixtures of 6-hydroxybicyclo[2.2.2]octan-2-ones is reviewed. Both steps, the preparation of the 3-oxocyclohexaneacetaldehyde and its cyclization were examined, as well as applications to the synthesis of natural products.
The intramolecular aldol condensation of 3-oxocyclohexaneacetaldehydes: a useful tool in the synthesis of natural products / Migneco, Luisa Maria; Leonelli, Francesca; MARINI BETTOLO, Rinaldo. - In: ARKIVOC. - ISSN 1551-7012. - ELETTRONICO. - VII:(2004), pp. 253-265.
The intramolecular aldol condensation of 3-oxocyclohexaneacetaldehydes: a useful tool in the synthesis of natural products
MIGNECO, Luisa Maria;LEONELLI, Francesca;MARINI BETTOLO, Rinaldo
2004
Abstract
The intramolecular aldol condensation of 3-oxocyclohexaneacetaldehydes leading to C(6) epimeric mixtures of 6-hydroxybicyclo[2.2.2]octan-2-ones is reviewed. Both steps, the preparation of the 3-oxocyclohexaneacetaldehyde and its cyclization were examined, as well as applications to the synthesis of natural products.File allegati a questo prodotto
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