The palladium-catalyzed hydroarylation of arenediazonium tetrafluoroborates with norbornene derivatives and analogues in the presence of Pd(OAc) 2 and i-Pr3SiH in THF affords hydroarylation products containing the added aryl unit in the exo position in good to high yields. The reaction tolerates a variety of useful functional groups and can be performed as a one-pot procedure generating the arenediazonium salt in situ. © Georg Thieme Verlag Stuttgart.
Aryl norbornanes and analogues via palladium-catalyzed hydroarylation with arenediazonium tetrafluoroborates / Gabriele, Bartoli; Cacchi, Sandro; Fabrizi, Giancarlo; Goggiamani, Antonella. - In: SYNLETT. - ISSN 0936-5214. - 2008:16(2008), pp. 2508-2512. [10.1055/s-2008-1078051]
Aryl norbornanes and analogues via palladium-catalyzed hydroarylation with arenediazonium tetrafluoroborates
CACCHI, Sandro;FABRIZI, Giancarlo;GOGGIAMANI, ANTONELLA
2008
Abstract
The palladium-catalyzed hydroarylation of arenediazonium tetrafluoroborates with norbornene derivatives and analogues in the presence of Pd(OAc) 2 and i-Pr3SiH in THF affords hydroarylation products containing the added aryl unit in the exo position in good to high yields. The reaction tolerates a variety of useful functional groups and can be performed as a one-pot procedure generating the arenediazonium salt in situ. © Georg Thieme Verlag Stuttgart.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
