In a previous paper we proposed a model to describe a gas of pyramidal molecules interacting via dipole-dipole interactions. The interaction modifies the tunneling properties between the classical equilibrium configurations of the sin- gle molecule and, for sufficiently high pressure, the molecules become localized in these classical configurations. The model explains quantitatively the shift to zero- frequency of the inversion line observed upon increase of the pressure in a gas of ammonia or deuterated ammonia. Here we analyze further the model especially with respect to stability questions.

Classical versus quantum structures: The case of pyramidal molecules / Presilla, Carlo; JONA LASINIO, Giovanni; Toninelli, C.. - 29:(2004), pp. 119-127. (Intervento presentato al convegno Meeting on Multiscale Methods in Quantum Mechanics tenutosi a Accademia Nazionale dei Lincei, Rome, Italy).

Classical versus quantum structures: The case of pyramidal molecules

PRESILLA, Carlo;JONA LASINIO, Giovanni;
2004

Abstract

In a previous paper we proposed a model to describe a gas of pyramidal molecules interacting via dipole-dipole interactions. The interaction modifies the tunneling properties between the classical equilibrium configurations of the sin- gle molecule and, for sufficiently high pressure, the molecules become localized in these classical configurations. The model explains quantitatively the shift to zero- frequency of the inversion line observed upon increase of the pressure in a gas of ammonia or deuterated ammonia. Here we analyze further the model especially with respect to stability questions.
2004
Meeting on Multiscale Methods in Quantum Mechanics
pyramidal molecules; Hund paradox; stability of chiral states
04 Pubblicazione in atti di convegno::04b Atto di convegno in volume
Classical versus quantum structures: The case of pyramidal molecules / Presilla, Carlo; JONA LASINIO, Giovanni; Toninelli, C.. - 29:(2004), pp. 119-127. (Intervento presentato al convegno Meeting on Multiscale Methods in Quantum Mechanics tenutosi a Accademia Nazionale dei Lincei, Rome, Italy).
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/210402
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