In a previous paper we proposed a model to describe a gas of pyramidal molecules interacting via dipole-dipole interactions. The interaction modifies the tunneling properties between the classical equilibrium configurations of the sin- gle molecule and, for sufficiently high pressure, the molecules become localized in these classical configurations. The model explains quantitatively the shift to zero- frequency of the inversion line observed upon increase of the pressure in a gas of ammonia or deuterated ammonia. Here we analyze further the model especially with respect to stability questions.
Classical versus quantum structures: The case of pyramidal molecules / Presilla, Carlo; JONA LASINIO, Giovanni; Toninelli, C.. - 29:(2004), pp. 119-127. (Intervento presentato al convegno Meeting on Multiscale Methods in Quantum Mechanics tenutosi a Accademia Nazionale dei Lincei, Rome, Italy).
Classical versus quantum structures: The case of pyramidal molecules
PRESILLA, Carlo;JONA LASINIO, Giovanni;
2004
Abstract
In a previous paper we proposed a model to describe a gas of pyramidal molecules interacting via dipole-dipole interactions. The interaction modifies the tunneling properties between the classical equilibrium configurations of the sin- gle molecule and, for sufficiently high pressure, the molecules become localized in these classical configurations. The model explains quantitatively the shift to zero- frequency of the inversion line observed upon increase of the pressure in a gas of ammonia or deuterated ammonia. Here we analyze further the model especially with respect to stability questions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.