The thermalproperties of the complexes of alanine, leucine and valine with several divalentmetalions [Co(II), Ni(II), Cu(II)] were determined using TG and DSC analyses and compared with those of analogous glycinate complexes. The thermal stability order of the series of complexes examined does not correlate with the Irving and Williams series for the stability of complexes in solution; however, a reverse correlation results with the order of basicity of the ligands.
Critical comparison of thermal properties of some divalent metal ion complexes with alanine, leucine and valine / Cardarelli, Enrico; Curini, Roberta; D'Ascenzo, Giuseppe; Tomassetti, Mauro. - In: THERMOCHIMICA ACTA. - ISSN 0040-6031. - STAMPA. - 113:(1987), pp. 243-255. [10.1016/0040-6031(87)88328-4]
Critical comparison of thermal properties of some divalent metal ion complexes with alanine, leucine and valine
CARDARELLI, Enrico;CURINI, Roberta;D'ASCENZO, Giuseppe;TOMASSETTI, Mauro
1987
Abstract
The thermalproperties of the complexes of alanine, leucine and valine with several divalentmetalions [Co(II), Ni(II), Cu(II)] were determined using TG and DSC analyses and compared with those of analogous glycinate complexes. The thermal stability order of the series of complexes examined does not correlate with the Irving and Williams series for the stability of complexes in solution; however, a reverse correlation results with the order of basicity of the ligands.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
