A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.
A photochemoenzymatic Hunsdiecker-Borodin-type halodecarboxylation of ferulic acid / Zippilli, C., Bartolome, M.J., Hilberath, T., Botta, L., Hollmann, F., Saladino, R.. - In: CHEMBIOCHEM. - ISSN 1439-7633. - 23:19(2022), pp. 1-4. [10.1002/cbic.202200367]
A photochemoenzymatic Hunsdiecker-Borodin-type halodecarboxylation of ferulic acid
Saladino, Raffaele
2022
Abstract
A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.File allegati a questo prodotto
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