We study two-dimensional triangular-network models, which have degenerate ground states composed of straight or randomly-zigzagging stripes and thus sub-extensive residual entropy. We show that attraction is responsible for the inversion of the stable phase by changing the entropy of fluctuations around the ground-state configurations. By using a real-space shell-expansion method, we compute the exact expression of the entropy for harmonic interactions, while for repulsive harmonic interactions we obtain the entropy arising from a limited subset of the system by numerical integration. We compare these results with a three-dimensional triangular-network model, which shows the same attraction-mediated selection mechanism of the stable phase, and conclude that this effect is general with respect to the dimensionality of the system.

Attraction Controls the Entropy of Fluctuations in Isosceles Triangular Networks / Leoni, Fabio; Shokef, Yair. - In: ENTROPY. - ISSN 1099-4300. - 20:2(2018). [10.3390/e20020122]

Attraction Controls the Entropy of Fluctuations in Isosceles Triangular Networks

Fabio Leoni
Primo
Membro del Collaboration Group
;
2018

Abstract

We study two-dimensional triangular-network models, which have degenerate ground states composed of straight or randomly-zigzagging stripes and thus sub-extensive residual entropy. We show that attraction is responsible for the inversion of the stable phase by changing the entropy of fluctuations around the ground-state configurations. By using a real-space shell-expansion method, we compute the exact expression of the entropy for harmonic interactions, while for repulsive harmonic interactions we obtain the entropy arising from a limited subset of the system by numerical integration. We compare these results with a three-dimensional triangular-network model, which shows the same attraction-mediated selection mechanism of the stable phase, and conclude that this effect is general with respect to the dimensionality of the system.
2018
order by disorder; geometric frustration; confined colloids; residual entropy
01 Pubblicazione su rivista::01a Articolo in rivista
Attraction Controls the Entropy of Fluctuations in Isosceles Triangular Networks / Leoni, Fabio; Shokef, Yair. - In: ENTROPY. - ISSN 1099-4300. - 20:2(2018). [10.3390/e20020122]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1753962
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