We are used to measuring temperature with a thermometer, and we know from everyday life that different types of thermometers measure the same temperature. This experience can be based on equilibrium thermodynamics, which explains the equivalence of different possibilities to define temperature. In contrast, for systems out of equilibrium such as active matter, measurements performed with different thermometers can generally lead to different temperature values. In the present work, we systematically compare different possibilities to define temperature for active systems. Based on simulations and theory for inertial active Brownian particles, we find that different temperatures generally lead to different temperature values, as expected. Remarkably, however, we find that different temperatures not only lead to the same values near equilibrium (low P & eacute;clet number or high particle mass) but also even far from equilibrium, several different temperatures approximately coincide. In particular, we find that the kinetic temperature, the configurational temperature, and temperatures based on higher moments of the velocity distribution constitute a class of temperatures that all assume very similar values over a wide parameter range. Notably, the effective temperature and temperatures exploiting the virial theorem, the Stokes-Einstein relation, or a harmonic confinement form a second class of temperatures whose values approximately coincide with each other but which strongly differ from those of the first class. Finally, we identify advantages and disadvantages of the different possibilities to define temperature and discuss their relevance for measuring the temperature of active systems.

How to define temperature in active systems? / Hecht, L.; Caprini, L.; Lowen, H.; Liebchen, B.. - In: JOURNAL OF CHEMICAL PHYSICS ONLINE. - ISSN 1089-7690. - 161:22(2024), pp. 1-16. [10.1063/5.0234370]

How to define temperature in active systems?

Caprini L.;
2024

Abstract

We are used to measuring temperature with a thermometer, and we know from everyday life that different types of thermometers measure the same temperature. This experience can be based on equilibrium thermodynamics, which explains the equivalence of different possibilities to define temperature. In contrast, for systems out of equilibrium such as active matter, measurements performed with different thermometers can generally lead to different temperature values. In the present work, we systematically compare different possibilities to define temperature for active systems. Based on simulations and theory for inertial active Brownian particles, we find that different temperatures generally lead to different temperature values, as expected. Remarkably, however, we find that different temperatures not only lead to the same values near equilibrium (low P & eacute;clet number or high particle mass) but also even far from equilibrium, several different temperatures approximately coincide. In particular, we find that the kinetic temperature, the configurational temperature, and temperatures based on higher moments of the velocity distribution constitute a class of temperatures that all assume very similar values over a wide parameter range. Notably, the effective temperature and temperatures exploiting the virial theorem, the Stokes-Einstein relation, or a harmonic confinement form a second class of temperatures whose values approximately coincide with each other but which strongly differ from those of the first class. Finally, we identify advantages and disadvantages of the different possibilities to define temperature and discuss their relevance for measuring the temperature of active systems.
2024
active matter; non-equilibrium statistical mechanics; soft matter
01 Pubblicazione su rivista::01a Articolo in rivista
How to define temperature in active systems? / Hecht, L.; Caprini, L.; Lowen, H.; Liebchen, B.. - In: JOURNAL OF CHEMICAL PHYSICS ONLINE. - ISSN 1089-7690. - 161:22(2024), pp. 1-16. [10.1063/5.0234370]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1747582
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