Non-Invasive Multi-Analytical Insights into Renaissance Wall Paintings by Bernardino Luini

The findings of non-invasive, multi-analytical research on two wall paintings located in the Santuario della Beata Vergine dei Miracoli in Saronno (Varese, Italy)—The Marriage of the Virgin and The Adoration of the Christ Child—are presented in this paper. The authorship of the latter is up for controversy, while the former is unquestionably attributed to Bernardino Luini. The objective was to assess the compatibility of their color palettes through material comparison. A complementary suite of non-invasive techniques, including X-ray fluorescence (XRF), external reflection FTIR, Raman, visible reflectance spectroscopy and hyperspectral imaging, were employed to characterize pigments and surface materials without sampling. Results confirm the use of historically consistent pigments such as calcium carbonate, ochres, Naples yellow, smalt, azurite and lapis lazuli. Differences in the application of blue pigments—lapis lazuli in The Marriage of the Virgin and azurite in The Adoration of the Christ Child—may reflect workshop variation rather than separate authorship. Spectral imaging revealed pigment mixing and layering strategies, especially in skin tones and shadow modeling. This study underscores the significance of diagnostics as an interpretive instrument, capable of contextualizin Luini’s paintings within the context of Renaissance creative practice, providing a framework relevant to analogous inquiries.