Heterogeneous mineralogical composition and fault behaviour: A systematic study in ternary fault rock compositions

The heterogeneous mineralogical compositions of fault gouges, formed during fault evolution, influence frictional properties and slip behaviour. While the influence of individual mineral phases on friction has been extensively studied, the impact of varying systematically mineral phases in gouge mixtures on macroscopic frictional behaviour remains unclear. Thus, we performed 34 frictional experiments on fault gouges composed of three representative mineral phases: muscovite (platy phyllosilicate), quartz (granular silicate) and calcite (granular carbonate), known for their markedly distinct frictional properties. Using a biaxial rock deformation apparatus (BRAVA), we performed tests on fault gouges with grain sizes <125 mu m under normal stresses of 50-100 MPa, at room temperature and water-saturated conditions. Our data indicate that the mineralogical composition of fault gouges significantly affects frictional strength, healing, and stability with a non-trivial pattern. Increasing the muscovite content leads to a decrease in frictional strength, from 0.62 for pure calcite and 0.56 for pure quartz to 0.33 of pure muscovite, along with reduced frictional healing and a velocity-strengthening behaviour. This weakening is promoted by a transition from localized deformation along discrete shear planes in granular-rich fault gouges to distributed deformation within the entire gouge layer with increasing muscovite content. At fixed muscovite content, frictional properties depend on the dominant granular phase. Calcite-dominated mixtures exhibit more marked frictional weakening rather than quartz-dominated ones, suggesting a non-linear mixing law between friction coefficient and muscovite content. This different trend is likely due to favourable conditions for fluid-assisted pressure-solution of calcite and foliation development, unlike quartz. When only the granular phases are mixed, we observe complex behaviour with the indentation of quartz into calcite, resulting in higher values of healing rates than those of pure end-member mixtures. Our findings provide robust insights into microphysical processes strongly dependent on the complex mineralogical compositions usually observed along natural faults.