We analyze the general relation between canonical and grand canonical ensembles in the thermodynamic limit. We begin our discussion by deriving, with an alternative approach, some standard results first obtained by Kac and coworkers in the late 1970s. Then, motivated by the Bose-Einstein condensation (BEC) of trapped gases with a fixed number of atoms, which is well described by the canonical ensemble and by the recent groundbreaking experimental realization of BEC with photons in a dye-filled optical microcavity under genuine grand canonical conditions, we apply our formalism to a system of non-interacting Bose particles confined in a two-dimensional harmonic trap. We discuss in detail the mathematical origin of the inequivalence of ensembles observed in the condensed phase, giving place to the so-called grand canonical catastrophe of density fluctuations. We also provide explicit analytical expressions for the internal energy and specific heat and compare them with available experimental data. For these quantities, we show the equivalence of ensembles in the thermodynamic limit.

Canonical vs. grand canonical ensemble for bosonic gases under harmonic confinement / Crisanti, Andrea; Salasnich, Luca; Sarracino, Alessandro; Zannetti, Marco. - In: ENTROPY. - ISSN 1099-4300. - 26:5(2024), pp. 1-25. [10.3390/e26050367]

Canonical vs. grand canonical ensemble for bosonic gases under harmonic confinement

Crisanti, Andrea;Sarracino, Alessandro;
2024

Abstract

We analyze the general relation between canonical and grand canonical ensembles in the thermodynamic limit. We begin our discussion by deriving, with an alternative approach, some standard results first obtained by Kac and coworkers in the late 1970s. Then, motivated by the Bose-Einstein condensation (BEC) of trapped gases with a fixed number of atoms, which is well described by the canonical ensemble and by the recent groundbreaking experimental realization of BEC with photons in a dye-filled optical microcavity under genuine grand canonical conditions, we apply our formalism to a system of non-interacting Bose particles confined in a two-dimensional harmonic trap. We discuss in detail the mathematical origin of the inequivalence of ensembles observed in the condensed phase, giving place to the so-called grand canonical catastrophe of density fluctuations. We also provide explicit analytical expressions for the internal energy and specific heat and compare them with available experimental data. For these quantities, we show the equivalence of ensembles in the thermodynamic limit.
2024
Bose–Einstein condensation; photons; statistical ensemble
01 Pubblicazione su rivista::01a Articolo in rivista
Canonical vs. grand canonical ensemble for bosonic gases under harmonic confinement / Crisanti, Andrea; Salasnich, Luca; Sarracino, Alessandro; Zannetti, Marco. - In: ENTROPY. - ISSN 1099-4300. - 26:5(2024), pp. 1-25. [10.3390/e26050367]
File allegati a questo prodotto
File Dimensione Formato  
Crisanti_Canonical_2024.pdf

accesso aperto

Note: Articolo su rivista
Tipologia: Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza: Creative commons
Dimensione 1.61 MB
Formato Adobe PDF
1.61 MB Adobe PDF

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1716261
Citazioni
  • ???jsp.display-item.citation.pmc??? 0
  • Scopus 0
  • ???jsp.display-item.citation.isi??? 0
social impact