Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle. © 2014 The Partner Organisations.
The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu / Pomarico, Giuseppe; Vecchi, Andrea; Mandoj, Fedeica; Bortolini, Olga; Cicero, Daniel Oscar; Galloni, Pierluca; Paolesse, Roberto. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 50:31(2014), pp. 4076-4078. [10.1039/c3cc49416k]
The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu
Pomarico, GiuseppePrimo
;
2014
Abstract
Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle. © 2014 The Partner Organisations.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
