We investigate the low-temperature properties of two-dimensional Lennard-Jones glass films, prepared in silico both by liquid cooling and by physical vapor deposition. We identify deep in the solid phase a crossover temperature T*, at which slow dynamics and enhanced heterogeneity emerge. Around T*, localized defects become visible, leading to vibrational anomalies as compared to standard solids. We find that, on average, T* decreases in samples with lower inherent structure energy, suggesting that such anomalies will be suppressed in ultrastable glass films, prepared both by very slow liquid cooling and vapor deposition.

Low-temperature anomalies of a vapor deposited glass / Seoane, B; Reid, Dr; de Pablo, Jj; Zamponi, F. - In: PHYSICAL REVIEW MATERIALS. - ISSN 2475-9953. - 2:1(2018). [10.1103/PhysRevMaterials.2.015602]

Low-temperature anomalies of a vapor deposited glass

Zamponi F
2018

Abstract

We investigate the low-temperature properties of two-dimensional Lennard-Jones glass films, prepared in silico both by liquid cooling and by physical vapor deposition. We identify deep in the solid phase a crossover temperature T*, at which slow dynamics and enhanced heterogeneity emerge. Around T*, localized defects become visible, leading to vibrational anomalies as compared to standard solids. We find that, on average, T* decreases in samples with lower inherent structure energy, suggesting that such anomalies will be suppressed in ultrastable glass films, prepared both by very slow liquid cooling and vapor deposition.
2018
Glass transition; fluctuations; statistical mechanics
01 Pubblicazione su rivista::01a Articolo in rivista
Low-temperature anomalies of a vapor deposited glass / Seoane, B; Reid, Dr; de Pablo, Jj; Zamponi, F. - In: PHYSICAL REVIEW MATERIALS. - ISSN 2475-9953. - 2:1(2018). [10.1103/PhysRevMaterials.2.015602]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1693850
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