We study the local dynamical fluctuations in glass-forming models of particles embedded in d-dimensional space, in the mean-field limit of d - ???. Our analytical calculation reveals that single-particle observables, such as squared particle displacements, display divergent fluctuations around the dynamical (or mode-coupling) transition, due to the emergence of nontrivial correlations between displacements along different directions. This effect notably gives rise to a divergent non-Gaussian parameter, ??2. The d - ??? local dynamics therefore becomes quite rich upon approaching the glass transition. The finite-d remnant of this phenomenon further provides a long sought-after, first-principle explanation for the growth of ??2 around the glass transition that is not based on multiparticle correlations.

Local dynamical heterogeneity in simple glass formers / Biroli, G., Charbonneau, P., Folena, G., Hu, Y., Zamponi, F.. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 128:17(2022), pp. 1-6. [10.1103/PhysRevLett.128.175501]

Local dynamical heterogeneity in simple glass formers

Zamponi F
2022

Abstract

We study the local dynamical fluctuations in glass-forming models of particles embedded in d-dimensional space, in the mean-field limit of d - ???. Our analytical calculation reveals that single-particle observables, such as squared particle displacements, display divergent fluctuations around the dynamical (or mode-coupling) transition, due to the emergence of nontrivial correlations between displacements along different directions. This effect notably gives rise to a divergent non-Gaussian parameter, ??2. The d - ??? local dynamics therefore becomes quite rich upon approaching the glass transition. The finite-d remnant of this phenomenon further provides a long sought-after, first-principle explanation for the growth of ??2 around the glass transition that is not based on multiparticle correlations.
2022
glass transition; fluctuations; statistical mechanics
01 Pubblicazione su rivista::01a Articolo in rivista
Local dynamical heterogeneity in simple glass formers / Biroli, G., Charbonneau, P., Folena, G., Hu, Y., Zamponi, F.. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 128:17(2022), pp. 1-6. [10.1103/PhysRevLett.128.175501]
File allegati a questo prodotto
File Dimensione Formato  
Biroli_Local-dynamical-heterogeneity_2022.pdf

solo gestori archivio

Note: Articolo su rivista
Tipologia: Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza: Tutti i diritti riservati (All rights reserved)
Dimensione 632.78 kB
Formato Adobe PDF
632.78 kB Adobe PDF   Contatta l'autore

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1693795
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 21
  • ???jsp.display-item.citation.isi??? 21
social impact