For the first time, CaV6O16·3H2O (CVO), synthesized via a highly efficient and fast microwave reaction, is used as a cathode material for aqueous zinc-ion batteries. Ex situ X-ray diffraction confirms the structure of this material to be stable upon reversible Zn2+ intercalation, due to its large interlayer distance (8.08 Å). The pillaring effect of calcium makes the as-prepared CVO an excellent Zn2+ cation host.
Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries / Liu, X., Zhang, H., Geiger, D., Han, J., Varzi, A., Kaiser, U., Moretti, A., Passerini, S.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 55:16(2019), pp. 2265-2268. [10.1039/c8cc07243d]
Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries
Passerini S.
Ultimo
2019
Abstract
For the first time, CaV6O16·3H2O (CVO), synthesized via a highly efficient and fast microwave reaction, is used as a cathode material for aqueous zinc-ion batteries. Ex situ X-ray diffraction confirms the structure of this material to be stable upon reversible Zn2+ intercalation, due to its large interlayer distance (8.08 Å). The pillaring effect of calcium makes the as-prepared CVO an excellent Zn2+ cation host.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
