Effect of ZnO-decorated electrospun veils on the damage tolerance of CFRP laminates

In this work, multifunctional carbon fiber reinforced polymer (CFRP) laminates were manufactured by interleaving electrospun veils decorated with ZnO nanorods (NRs) (CFRP_NY_ZnO). The laminates were tested under dynamic (low velocity impact at 5.0 J and 7.5 J) and quasi-static (pre- and post-impact four-point bending tests) loading conditions. The delamination resistance of CFRP_NY_ZnO was compared with those of CFRP (without veils) and CFRP_NY (with four non-decorated veils) laminates. At 5.0 J, ZnO NRs enhanced the delamination resistance (the lowest delaminated area was around 232.3 ± 38.7 mm2) due to additional energy consuming mechanisms. When the impact energy was increased (7.5 J), the debonding of ZnO NRs from the nanofibers was promoted and a rapid failure propagation was observed (increase in delaminated area of about 27% with respect to CFRP_NY). In quasi-static condition, ZnO NRs proved to be effective in increasing flexural strength (914.4 MPa (±18.8 MPa)) and modulus (83.6 GPa (±0.3 GPa)) of the laminate with respect to CFRP and CFRP_NY and in preventing laminate stiffness losses even after impacts at 5.0 J and 7.5 J.