: Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard® 3401) with a commercially available functional group (Fumion® FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO2 absorption on membrane conductivity.

Synthesis and characterization of a composite anion exchange membrane for water electrolyzers (AEMWE) / Rakhshani, Somayyeh; Araneo, Rodolfo; Pucci, Andrea; Rinaldi, Antonio; Giuliani, Chiara; Pozio, Alfonso. - In: MEMBRANES. - ISSN 2077-0375. - 13:1(2023), pp. 1-15. [10.3390/membranes13010109]

Synthesis and characterization of a composite anion exchange membrane for water electrolyzers (AEMWE)

Somayyeh Rakhshani;Rodolfo ARANEO;
2023

Abstract

: Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard® 3401) with a commercially available functional group (Fumion® FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO2 absorption on membrane conductivity.
2023
alkaline water electrolysis; anion exchange membrane; membrane characterization
01 Pubblicazione su rivista::01a Articolo in rivista
Synthesis and characterization of a composite anion exchange membrane for water electrolyzers (AEMWE) / Rakhshani, Somayyeh; Araneo, Rodolfo; Pucci, Andrea; Rinaldi, Antonio; Giuliani, Chiara; Pozio, Alfonso. - In: MEMBRANES. - ISSN 2077-0375. - 13:1(2023), pp. 1-15. [10.3390/membranes13010109]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1666886
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