Hydrogen and deuterium solubility, diffusivity and permeability from sorption measurements in the Ni33Ti39Nb28 alloy

The hydrogen/deuterium sorption properties of Ni33Ti39Nb28 synthesized by the vacuum induction melting technique were measured between 400 and 495 C for pressure lower than 3 bar. The Sieverts law is valid up to H(D)/M < 0.2 in its ideal form; the absolute values of the hydrogenation/deuteration enthalpy are DH(H2) = 85+-5 kJ/mol and DH(D2) = 84+-4 kJ/mol. From the kinetics of absorption, the diffusion coefficient was derived, and an Arrhenius dependence from the temperature was obtained, with Ea,d = 12+-1 kJ/mol for both hydrogen isotopes. The values of the alloy permeability, obtained by combining the solubility and the diffusion coefficient, were of the order of 10^(-9) mol m^(-1) s^(-1) Pa^(-0).5, a value which is one order of magnitude lower than that of Ni41Ti42Nb17, until now the best Ni-Ti-Nb alloy for hydrogen purification. In view of the simplicity of the technique here proposed to calculate the permeability, this method could be used for the preliminary screening of new alloys.