We present the first evidence by acoustic measurements of H tunneling and trapping by 0 atoms in a rare-earth-hydride system. The YO00027HOO]6 alloy presents three new elastic-energy-loss peaks most likely due to H trapped by 0 between 1.4 and 330 K. The peak at the lowest temperature is due to tunneling of the trapped H; its relaxation rate strongly depends on temperature, indicating a dominant contribution of multiphonon processes already at a few kelvin. The other two peaks, with activation energies of 0.14 and 0.22 eV, can be attributed to jumps of H in the distorted environment of the 0 atom.
H tunneling and trapping in Y by anelastic relaxation measurements / Cannelli, G.; Cantelli, R.; Cordero, F.; Trequattrini, F.; Anderson, I. S.; Rush, J. J.. - In: PHYSICAL REVIEW LETTERS. - ISSN 0031-9007. - 67:19(1991), pp. 2682-2685. [10.1103/PhysRevLett.67.2682]
H tunneling and trapping in Y by anelastic relaxation measurements
Cannelli, G.;Cantelli, R.;Trequattrini, F.;
1991
Abstract
We present the first evidence by acoustic measurements of H tunneling and trapping by 0 atoms in a rare-earth-hydride system. The YO00027HOO]6 alloy presents three new elastic-energy-loss peaks most likely due to H trapped by 0 between 1.4 and 330 K. The peak at the lowest temperature is due to tunneling of the trapped H; its relaxation rate strongly depends on temperature, indicating a dominant contribution of multiphonon processes already at a few kelvin. The other two peaks, with activation energies of 0.14 and 0.22 eV, can be attributed to jumps of H in the distorted environment of the 0 atom.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.