A large number of metal artifacts with exceptional artistic value of the Moche culture have been found in the tombs of the Lords of Sipán (Lambayeque, Peru) and of the Lady of Cao (El Brujo, Peru) characterized by different burial conditions. Some of the objects, dated around 300-400 AD, are constituted by substrates of Cu- or Ag-based alloys coated by uniformly distributed thin films of precious metal (1-4 microns) that create also polymetallic bicolored surfaces with “gold” and “silver” areas. In order to investigate the corrosion product structure and composition as well as to identify the techniques used to give the gold or silver appearance, an integrated analytical approach has been adopted. The selected complementary methodologies were scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and optical microscopy (OM). The findings reveal that the substrates are mainly composed of Cu-Ag-Au alloys that at the site of Sipán have been almost completely corroded during the burial. Furthermore, the results show that the main aggressive agent is Cl- coming from the soil and that the degradation phenomena were likely enhanced by the galvanic coupling between the precious metal layer and the less noble substrate. The degradation products have formed mainly layered structures containing chloroargyrite (AgCl), cuprite (Cu2O), nantokite (CuCl), and atacamite [CuCl2:3Cu(OH)2] polymorphs. These latter species warn that dangerous copper cyclic corrosion is occurring, a harmful phenomenon, commonly defined as “bronze disease,” which must be firmly mitigated. Finally, the findings reveal that the Moche metal workers used the depletion gilding to selectively modify the surface chemical composition of the artifacts to produce the Ag or Au thin films. According to this subtractive method, the surface of the Cu-Au-Ag alloys was enriched with a layer of precious metal by means of cycles of thermal treatments and removal of Cu or both Cu and Ag from the outermost region by using pickling solutions.

Microchemical investigation of long-term buried gilded and silvered artifacts from ancient Peru / Ingo, Gabriel M.; Albini, Monica; Bustamante, Angel D.; Sandra del Pilar Zambrano, Alva; Fernandez, Arabel; Giuliani, Chiara; Messina, Elena; Pascucci, Marianna; Riccucci, Cristina; Staccioli, MARIA PAOLA; Di Carlo, Gabriella; Tortora, Luca. - In: FRONTIERS IN CHEMISTRY. - ISSN 2296-2646. - 7:(2020), pp. 1-13. [10.3389/fmats.2020.00230]

Microchemical investigation of long-term buried gilded and silvered artifacts from ancient Peru

Gabriel M. Ingo
;
Elena Messina;Maria Paola Staccioli;
2020

Abstract

A large number of metal artifacts with exceptional artistic value of the Moche culture have been found in the tombs of the Lords of Sipán (Lambayeque, Peru) and of the Lady of Cao (El Brujo, Peru) characterized by different burial conditions. Some of the objects, dated around 300-400 AD, are constituted by substrates of Cu- or Ag-based alloys coated by uniformly distributed thin films of precious metal (1-4 microns) that create also polymetallic bicolored surfaces with “gold” and “silver” areas. In order to investigate the corrosion product structure and composition as well as to identify the techniques used to give the gold or silver appearance, an integrated analytical approach has been adopted. The selected complementary methodologies were scanning electron microscopy (SEM) coupled with energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and optical microscopy (OM). The findings reveal that the substrates are mainly composed of Cu-Ag-Au alloys that at the site of Sipán have been almost completely corroded during the burial. Furthermore, the results show that the main aggressive agent is Cl- coming from the soil and that the degradation phenomena were likely enhanced by the galvanic coupling between the precious metal layer and the less noble substrate. The degradation products have formed mainly layered structures containing chloroargyrite (AgCl), cuprite (Cu2O), nantokite (CuCl), and atacamite [CuCl2:3Cu(OH)2] polymorphs. These latter species warn that dangerous copper cyclic corrosion is occurring, a harmful phenomenon, commonly defined as “bronze disease,” which must be firmly mitigated. Finally, the findings reveal that the Moche metal workers used the depletion gilding to selectively modify the surface chemical composition of the artifacts to produce the Ag or Au thin films. According to this subtractive method, the surface of the Cu-Au-Ag alloys was enriched with a layer of precious metal by means of cycles of thermal treatments and removal of Cu or both Cu and Ag from the outermost region by using pickling solutions.
2020
Cu-Ag-Au ternary alloys; long-term burial soil corrosion; surface analytical techniques; metal surface chemical modification; galvanic coupling; tumbaga
01 Pubblicazione su rivista::01a Articolo in rivista
Microchemical investigation of long-term buried gilded and silvered artifacts from ancient Peru / Ingo, Gabriel M.; Albini, Monica; Bustamante, Angel D.; Sandra del Pilar Zambrano, Alva; Fernandez, Arabel; Giuliani, Chiara; Messina, Elena; Pascucci, Marianna; Riccucci, Cristina; Staccioli, MARIA PAOLA; Di Carlo, Gabriella; Tortora, Luca. - In: FRONTIERS IN CHEMISTRY. - ISSN 2296-2646. - 7:(2020), pp. 1-13. [10.3389/fmats.2020.00230]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1657570
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