Various terminal olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields by potassium permanganate oxidation. The reaction is also highly chemoselective in the presence of differently protected hydroxy groups and can be utilised for the preparation of polyfunctional compounds such as polyols.
New functionalised hydroxymethyl ketones from the mild and chemoselective KMnO4 oxidation of chiral terminal olefins / Bonini, Carlo Cesare; Chiummiento, Lucia; Funicello, Maria; Lupattelli, Paolo; Pullez, M.. - In: EUROPEAN JOURNAL OF ORGANIC CHEMISTRY. - ISSN 1434-193X. - (2006), pp. 80-83. [10.1002/ejoc.200500737]
New functionalised hydroxymethyl ketones from the mild and chemoselective KMnO4 oxidation of chiral terminal olefins
BONINI, Carlo Cesare;LUPATTELLI, Paolo;
2006
Abstract
Various terminal olefinic compounds are directly converted into the corresponding α-hydroxy ketones in good yields by potassium permanganate oxidation. The reaction is also highly chemoselective in the presence of differently protected hydroxy groups and can be utilised for the preparation of polyfunctional compounds such as polyols.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
