The power conversion efficiency of the formamidinium tin iodide (FASI) solar cells constantly increases, with the current record power conversion efficiency approaching 15%. The literature reports a broad anomaly distribution of the photoluminescence (PL) peak position. The PL anomaly is particularly relevant to photovoltaic applications since it directly links the material's bandgap and subgap defects energy, which are crucial to extracting its full photovoltaic potential. Herein, the PL of FASI polycrystalline thin film and powder is studied. It is found that a distribution of PL peak positions in line with the distribution available in the literature systematically. The distribution in PL is linked to the octahedral tilting and Sn off-centering within the perovskite lattice, influenced by the procedure used to prepare the material. Our finding paves the way toward controlling the energy distribution of tin perovskite and thus preparing highly efficient tin halide perovskite solar cells.

Energy Distribution in Tin Halide Perovskite / Di Girolamo, D.; Blundo, E.; Folpini, G.; Ponti, C.; Li, G.; Aldamasy, M. H.; Iqbal, Z.; Pascual, J.; Nasti, G.; Li, M.; Avolio, R.; Russina, O.; Latini, A.; Alharthi, F.; Felici, M.; Petrozza, A.; Polimeni, A.; Abate, A.. - In: SOLAR RRL. - ISSN 2367-198X. - (2021), p. 2100825. [10.1002/solr.202100825]

Energy Distribution in Tin Halide Perovskite

Blundo E.;Russina O.;Latini A.;Felici M.;Polimeni A.;
2021

Abstract

The power conversion efficiency of the formamidinium tin iodide (FASI) solar cells constantly increases, with the current record power conversion efficiency approaching 15%. The literature reports a broad anomaly distribution of the photoluminescence (PL) peak position. The PL anomaly is particularly relevant to photovoltaic applications since it directly links the material's bandgap and subgap defects energy, which are crucial to extracting its full photovoltaic potential. Herein, the PL of FASI polycrystalline thin film and powder is studied. It is found that a distribution of PL peak positions in line with the distribution available in the literature systematically. The distribution in PL is linked to the octahedral tilting and Sn off-centering within the perovskite lattice, influenced by the procedure used to prepare the material. Our finding paves the way toward controlling the energy distribution of tin perovskite and thus preparing highly efficient tin halide perovskite solar cells.
2021
lead-free perovskites; perovskite solar cells; photoluminescence
01 Pubblicazione su rivista::01a Articolo in rivista
Energy Distribution in Tin Halide Perovskite / Di Girolamo, D.; Blundo, E.; Folpini, G.; Ponti, C.; Li, G.; Aldamasy, M. H.; Iqbal, Z.; Pascual, J.; Nasti, G.; Li, M.; Avolio, R.; Russina, O.; Latini, A.; Alharthi, F.; Felici, M.; Petrozza, A.; Polimeni, A.; Abate, A.. - In: SOLAR RRL. - ISSN 2367-198X. - (2021), p. 2100825. [10.1002/solr.202100825]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1603258
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