We report on the self-assembly of core–shell Ge/In–Te nanowires (NWs) on single crystal Si substrates by Metalorganic Chemical Vapour Deposition (MOCVD), coupled to the Vapour–Liquid–Solid (VLS) mechanism, catalysed by Au nanoparticles (NPs). The NWs are formed by a crystalline Ge core and an InTe (II) shell, have diameters down to 15 nm and show <110> oriented growth direction. The role of the MOCVD process parameters and of the NPs size in determining the NWs core–shell microstructure and their alignment was investigated by high-resolution TEM, EDX, XRD and Raman spectroscopy. IMPACT STATEMENT A novel one-step MOCVD growth procedure, yielding self-assembled, oriented and crystalline core–shell Ge/In–Te nanowires with diameters down to 15 nm, along with their chemical–physical characterization.

Single-step Au-catalysed synthesis and microstructural characterization of core–shell Ge/In–Te nanowires by MOCVD / Cecchini, R.; Selmo, S.; Wiemer, C.; Rotunno, E.; Lazzarini, L.; De Luca, M.; Zardo, I.; Longo, M.. - In: MATERIALS RESEARCH LETTERS. - ISSN 2166-3831. - 6:1(2018), pp. 29-35. [10.1080/21663831.2017.1384409]

Single-step Au-catalysed synthesis and microstructural characterization of core–shell Ge/In–Te nanowires by MOCVD

De Luca M.;
2018

Abstract

We report on the self-assembly of core–shell Ge/In–Te nanowires (NWs) on single crystal Si substrates by Metalorganic Chemical Vapour Deposition (MOCVD), coupled to the Vapour–Liquid–Solid (VLS) mechanism, catalysed by Au nanoparticles (NPs). The NWs are formed by a crystalline Ge core and an InTe (II) shell, have diameters down to 15 nm and show <110> oriented growth direction. The role of the MOCVD process parameters and of the NPs size in determining the NWs core–shell microstructure and their alignment was investigated by high-resolution TEM, EDX, XRD and Raman spectroscopy. IMPACT STATEMENT A novel one-step MOCVD growth procedure, yielding self-assembled, oriented and crystalline core–shell Ge/In–Te nanowires with diameters down to 15 nm, along with their chemical–physical characterization.
2018
core–shell nanowires; Germanium; MOCVD; single step; VLS
01 Pubblicazione su rivista::01a Articolo in rivista
Single-step Au-catalysed synthesis and microstructural characterization of core–shell Ge/In–Te nanowires by MOCVD / Cecchini, R.; Selmo, S.; Wiemer, C.; Rotunno, E.; Lazzarini, L.; De Luca, M.; Zardo, I.; Longo, M.. - In: MATERIALS RESEARCH LETTERS. - ISSN 2166-3831. - 6:1(2018), pp. 29-35. [10.1080/21663831.2017.1384409]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1558082
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