Anomalous deviations from the Beer-Lambert law have been observed for a long time in a wide range of application. Despite all the attempts, a reliable and accepted model has not been provided so far. In addition, in some cases the attenuation of radiation seems to follow a hyperbolic more than an exponential extinction law. Starting from a probabilistic interpretation of the Beer-Lambert law based on Poissonian distribution of extinction events, in this paper we consider deviations from the classical exponential extinction introducing a weighted version of the classical law. The generalized law is able to account for both sub or super-exponential extinction of radiation, and can be extended to the case of inhomogeneous media. Focusing on this case, we consider a generalized Beer-Lambert law based on an inhomogeneous weighted Poisson distribution involving a Mittag-Leffler function, and show how it can be directly related to hyperbolic decay laws observed in some applications particularly relevant to microbiology and pharmacology.
Towards a generalized beer-lambert law / Casasanta, G.; Garra, R.. - In: FRACTAL AND FRACTIONAL. - ISSN 2504-3110. - 2:1(2018), pp. 1-7. [10.3390/fractalfract2010008]
Towards a generalized beer-lambert law
Casasanta G.;Garra R.
2018
Abstract
Anomalous deviations from the Beer-Lambert law have been observed for a long time in a wide range of application. Despite all the attempts, a reliable and accepted model has not been provided so far. In addition, in some cases the attenuation of radiation seems to follow a hyperbolic more than an exponential extinction law. Starting from a probabilistic interpretation of the Beer-Lambert law based on Poissonian distribution of extinction events, in this paper we consider deviations from the classical exponential extinction introducing a weighted version of the classical law. The generalized law is able to account for both sub or super-exponential extinction of radiation, and can be extended to the case of inhomogeneous media. Focusing on this case, we consider a generalized Beer-Lambert law based on an inhomogeneous weighted Poisson distribution involving a Mittag-Leffler function, and show how it can be directly related to hyperbolic decay laws observed in some applications particularly relevant to microbiology and pharmacology.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.