In this Perspective, we provide an overview of the pressure-induced effects on hybrid organic-inorganic perovskite for photovoltaics applications. It is shown that a fine-tuning of the most relevant photovoltaic properties, including band gap and carrier lifetime, is indeed possible by applying pressure over a rather small range and that such phenomena closely correlate with pressure-induced structural changes. High-pressure research can be used to search for new materials since the high-pressure structural configuration can be used as a model for tailoring ambient pressure compounds under proper chemical substitution, and the band gap tuning and enhancement of carrier lifetime with applied pressures can be a guide to design new hybrid perovskites with desired optical properties as a function of structural parameters.

Pressure-induced effects in organic-inorganic hybrid Perovskites / Postorino, P.; Malavasi, L.. - In: THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS. - ISSN 1948-7185. - 8:12(2017), pp. 2613-2622. [10.1021/acs.jpclett.7b00347]

Pressure-induced effects in organic-inorganic hybrid Perovskites

Postorino P.;
2017

Abstract

In this Perspective, we provide an overview of the pressure-induced effects on hybrid organic-inorganic perovskite for photovoltaics applications. It is shown that a fine-tuning of the most relevant photovoltaic properties, including band gap and carrier lifetime, is indeed possible by applying pressure over a rather small range and that such phenomena closely correlate with pressure-induced structural changes. High-pressure research can be used to search for new materials since the high-pressure structural configuration can be used as a model for tailoring ambient pressure compounds under proper chemical substitution, and the band gap tuning and enhancement of carrier lifetime with applied pressures can be a guide to design new hybrid perovskites with desired optical properties as a function of structural parameters.
2017
High-pressure; photovoltaics; hybrid perovskites
01 Pubblicazione su rivista::01a Articolo in rivista
Pressure-induced effects in organic-inorganic hybrid Perovskites / Postorino, P.; Malavasi, L.. - In: THE JOURNAL OF PHYSICAL CHEMISTRY LETTERS. - ISSN 1948-7185. - 8:12(2017), pp. 2613-2622. [10.1021/acs.jpclett.7b00347]
File allegati a questo prodotto
File Dimensione Formato  
Postorino_Pressure-induced-effects.pdf

solo gestori archivio

Tipologia: Versione editoriale (versione pubblicata con il layout dell'editore)
Licenza: Tutti i diritti riservati (All rights reserved)
Dimensione 5.21 MB
Formato Adobe PDF
5.21 MB Adobe PDF   Contatta l'autore

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1517667
Citazioni
  • ???jsp.display-item.citation.pmc??? 8
  • Scopus 82
  • ???jsp.display-item.citation.isi??? 83
social impact