Oxidative addition of MeI to an Ir(I) centre is 4-120 times faster than that to an analogous Rh(I) centre, whereas the migration of methyl onto coordinated CO in the cor-responding systems is 10(5)-10(6) times faster for Rh(III) than Ir(III).
RELATIVE REACTION-RATES FOR RHODIUM AND IRIDIUM - OXIDATIVE ADDITION OF METHYL-IODIDE TO M(I) AND THE MIGRATORY INSERTION IN M(III) METHYL CARBONYL-COMPLEXES / Bassetti, M; Monti, D; Haynes, A; Pearson, Jm; Stanbridge, Ia; Maitlis, Pm. - In: GAZZETTA CHIMICA ITALIANA. - ISSN 0016-5603. - 122:9(1992), pp. 391-393.
RELATIVE REACTION-RATES FOR RHODIUM AND IRIDIUM - OXIDATIVE ADDITION OF METHYL-IODIDE TO M(I) AND THE MIGRATORY INSERTION IN M(III) METHYL CARBONYL-COMPLEXES
MONTI D;
1992
Abstract
Oxidative addition of MeI to an Ir(I) centre is 4-120 times faster than that to an analogous Rh(I) centre, whereas the migration of methyl onto coordinated CO in the cor-responding systems is 10(5)-10(6) times faster for Rh(III) than Ir(III).File allegati a questo prodotto
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