The oxidation of purine derivatives using porphyrins as catalysts and dimethyldioxirane (DMDO) as oxygen atom donor is reported. The regioselectivity of the oxidation was found to be dependent on the presence of a free OH moiety on the N(9)-side chain of the substrate and on the structure of the catalyst.
Manganese tetraphenylporphyrins catalyzed selective oxidation of purine derivatives / Saladino, R; Carlucci, P; Crestini, C; Tagliatesta, P; Monti, D; Boschi, T. - In: NUCLEOSIDES & NUCLEOTIDES. - ISSN 0732-8311. - 18:4-5(1999), pp. 1123-1124. [10.1080/15257779908041665]
Manganese tetraphenylporphyrins catalyzed selective oxidation of purine derivatives
Monti D;
1999
Abstract
The oxidation of purine derivatives using porphyrins as catalysts and dimethyldioxirane (DMDO) as oxygen atom donor is reported. The regioselectivity of the oxidation was found to be dependent on the presence of a free OH moiety on the N(9)-side chain of the substrate and on the structure of the catalyst.File allegati a questo prodotto
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