A diiminoisoindolo-pyrazino unit was annulated to the β-pyrrolic position of the Zn complex of tetraphenylporphyrin, giving a macrocycle with an expanded π system in satisfactory yields. The crystal structure of this derivative evidenced the formation of a hydrogen bond network. The interaction of the β-fused isoindoline porphyrin derivative with nucleotides and nucleic acids has been investigated. © 2016 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
The interaction of a β-fused isoindoline-porphyrin conjugate with nucleic acids / Mandoj, Federica; D’Urso, Alessandro; Nardis, Sara; Monti, Donato; Stefanelli, Manuela; Gangemi, Chiara M. A.; Randazzo, Rosalba; Fronczek, Frank R.; Smith, Kevin M.; Paolesse, Roberto. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 40:7(2016), pp. 5662-5665. [10.1039/c5nj03201f]
The interaction of a β-fused isoindoline-porphyrin conjugate with nucleic acids
Monti, Donato;
2016
Abstract
A diiminoisoindolo-pyrazino unit was annulated to the β-pyrrolic position of the Zn complex of tetraphenylporphyrin, giving a macrocycle with an expanded π system in satisfactory yields. The crystal structure of this derivative evidenced the formation of a hydrogen bond network. The interaction of the β-fused isoindoline porphyrin derivative with nucleotides and nucleic acids has been investigated. © 2016 The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.| File | Dimensione | Formato | |
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