The solidification of small parahydrogen clusters containing a foreign, nonspherical molecule at their centre (in particular OCS, as in the important Gottingen superfluidity experiment), is studied. The foreign molecule (a) partly replaces the solid phase, (b) imposes a nonspherical symmetry to the solid-liquid interface, (c) furnishes a template for solidification, (d) promotes solidification via its van der Waals attraction. By far the most important is the last-mentioned effect (at least for a strongly interacting molecule such as OCS). As a result, the solidification times are drastically reduced with respect to the case of pure hydrogen clusters. Some relationship with the experiment is discussed.
Solidification of hydrogen clusters including a foreign molecule / Mazzarello, R; Levi, Ac. - In: JOURNAL OF LOW TEMPERATURE PHYSICS. - ISSN 0022-2291. - 127:5-6(2002), pp. 259-269. [10.1023/A:1015239020248]
Solidification of hydrogen clusters including a foreign molecule
Mazzarello R;
2002
Abstract
The solidification of small parahydrogen clusters containing a foreign, nonspherical molecule at their centre (in particular OCS, as in the important Gottingen superfluidity experiment), is studied. The foreign molecule (a) partly replaces the solid phase, (b) imposes a nonspherical symmetry to the solid-liquid interface, (c) furnishes a template for solidification, (d) promotes solidification via its van der Waals attraction. By far the most important is the last-mentioned effect (at least for a strongly interacting molecule such as OCS). As a result, the solidification times are drastically reduced with respect to the case of pure hydrogen clusters. Some relationship with the experiment is discussed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.