The PhIO promoted oxidation of N-methyl-9-t-butylacridane (1) catalyzed by tetrakis(pentafluorophenyl) porphyrin iron(III) leads first to 9-t-butylacridane and then to acridine. It is suggested that 1 can represent a reliable machanistic probe to detect the intervention of radical cations in the oxidation of aromatic amines. (C) 1999 Elsevier Science Ltd. All rights reserved.
Oxidation of N-Methyl-9-t-butylacridane by Iodosylbenzene Catalyzed by Tetrakis(pentafluorophenyl) Porphyrin Iron(III). A Tool to Investigate the Mechanism of the Biomimetic N-Demethylation of Aromatic Tertiary Amines / Baciocchi, Enrico; Lapi, Andrea. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - STAMPA. - 40:(1999), pp. 5425-5428. [10.1016/S0040-4039(99)01023-0]
Oxidation of N-Methyl-9-t-butylacridane by Iodosylbenzene Catalyzed by Tetrakis(pentafluorophenyl) Porphyrin Iron(III). A Tool to Investigate the Mechanism of the Biomimetic N-Demethylation of Aromatic Tertiary Amines.
BACIOCCHI, Enrico;LAPI, Andrea
1999
Abstract
The PhIO promoted oxidation of N-methyl-9-t-butylacridane (1) catalyzed by tetrakis(pentafluorophenyl) porphyrin iron(III) leads first to 9-t-butylacridane and then to acridine. It is suggested that 1 can represent a reliable machanistic probe to detect the intervention of radical cations in the oxidation of aromatic amines. (C) 1999 Elsevier Science Ltd. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
