The photophysical properties of two atropisomeric naphthalenophanes (1 and 2) have been studied. Their structure only differs in the relative arrangement, syn (1) or anti (2), of the two aromatic units. The compounds emission is mainly excimeric and is strongly quenched in the presence of oxygen. Comparison of emission intensities obtained from steady state and from decay times provides clear evidence of the formation of ground state charge transfer complexes between oxygen and the naphthalenophanes 1 and 2. The calculated values for the association constants are on the order of 10(3) M(-1) (ethanol, room temperature) for both naphthalenophanes.
Unusual reversible complexation between atropisomeric naphthalenophanes and molecular oxygen / Laura, Rodríguez; JOÃO C., Lima; Fernando, Pina; Roberta, Cacciapaglia; DI STEFANO, Stefano; Albert, Ruggi. - In: JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY. - ISSN 1089-5639. - STAMPA. - 115:(2011), pp. 123-127. [10.1021/jp106887c]
Unusual reversible complexation between atropisomeric naphthalenophanes and molecular oxygen
DI STEFANO, Stefano;
2011
Abstract
The photophysical properties of two atropisomeric naphthalenophanes (1 and 2) have been studied. Their structure only differs in the relative arrangement, syn (1) or anti (2), of the two aromatic units. The compounds emission is mainly excimeric and is strongly quenched in the presence of oxygen. Comparison of emission intensities obtained from steady state and from decay times provides clear evidence of the formation of ground state charge transfer complexes between oxygen and the naphthalenophanes 1 and 2. The calculated values for the association constants are on the order of 10(3) M(-1) (ethanol, room temperature) for both naphthalenophanes.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
