(+)-syn-Benzotriborneol forms stable complexes with one molecule of water. This is due to the ability of the host to form three hydrogen bonds with water, to act simultaneously as a hydrogen-bond acceptor and donor, and to a perfect geometrical match between the pair. We report experimental (X-ray and neutron diffraction, VT NMR, DSC, TGA) and stereochemical studies carried out to elucidate and quantify the molecular and thermodynamic aspects of this supramolecular complex. © The Royal Society of Chemistry 2012.
(+)-syn-Benzotriborneol an enantiopure C 3-symmetric receptor for water / Fabris, F.; De Lucchi, O.; Nardini, I.; Crisma, M.; Mazzanti, A.; Mason, S. A.; Lemee-Cailleau, M. -H.; Scaramuzzo, F. A.; Zonta, C.. - In: ORGANIC & BIOMOLECULAR CHEMISTRY. - ISSN 1477-0520. - 10:12(2012), pp. 2464-2469. [10.1039/c2ob06774a]
(+)-syn-Benzotriborneol an enantiopure C 3-symmetric receptor for water
Scaramuzzo F. A.;
2012
Abstract
(+)-syn-Benzotriborneol forms stable complexes with one molecule of water. This is due to the ability of the host to form three hydrogen bonds with water, to act simultaneously as a hydrogen-bond acceptor and donor, and to a perfect geometrical match between the pair. We report experimental (X-ray and neutron diffraction, VT NMR, DSC, TGA) and stereochemical studies carried out to elucidate and quantify the molecular and thermodynamic aspects of this supramolecular complex. © The Royal Society of Chemistry 2012.| File | Dimensione | Formato | |
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