The synthesis and characterization of three new indium phthalocyanines bearing eight N-alkyl- or N-arylsulfonamide groups is described. The new compounds are {2,3,9,10,16,17,23,24-octakis[4-(4-methoxyphenylaminosulfonyl] phenoxy]phthalocyaninato}indium(III) chloride (7), {2,3,9,10,16,17,23,24- octakis[4-diethylaminosulfonyl)phenoxy]phthalocyaninato}indium(III) chloride (8) and {2,3,9,10,16,17,23,24-octakis[4-didodecylaminosulfonyl)phenoxy] phthalocyaninato}indium(III) chloride (9), and were obtained in 23-49% yields. The precursors of phthalocyanines 7-9 are sulfonamide-substituted phthalonitriles that can be prepared by reacting 4,5-bis(4- chlorosulfonylphenoxy)phthalonitrile (3) with amines. The nonlinear transmission (NLT) of complexes 7-9 was determined at 532 nm using ns pulses. All three phthalocyanines behave as reverse saturable absorbers with increasing efficiency of optical limiting in the order 7 < 8 < 9. A comparative analysis of the NLT results is attempted in terms of the structural differences in 7-9. © 2010 Elsevier B.V. All rights reserved.

Synthesis and high ranked NLT properties of new sulfonamide-substituted indium phthalocyanines / Efa, Carvalho; Mjf, Calvete; Jose A. S., Cavaleiro; Dini, Danilo; Moreno, Meneghetti; Augusto C., Tome. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 363:14(2010), pp. 3945-3950. [10.1016/j.ica.2010.07.062]

Synthesis and high ranked NLT properties of new sulfonamide-substituted indium phthalocyanines

DINI, DANILO;
2010

Abstract

The synthesis and characterization of three new indium phthalocyanines bearing eight N-alkyl- or N-arylsulfonamide groups is described. The new compounds are {2,3,9,10,16,17,23,24-octakis[4-(4-methoxyphenylaminosulfonyl] phenoxy]phthalocyaninato}indium(III) chloride (7), {2,3,9,10,16,17,23,24- octakis[4-diethylaminosulfonyl)phenoxy]phthalocyaninato}indium(III) chloride (8) and {2,3,9,10,16,17,23,24-octakis[4-didodecylaminosulfonyl)phenoxy] phthalocyaninato}indium(III) chloride (9), and were obtained in 23-49% yields. The precursors of phthalocyanines 7-9 are sulfonamide-substituted phthalonitriles that can be prepared by reacting 4,5-bis(4- chlorosulfonylphenoxy)phthalonitrile (3) with amines. The nonlinear transmission (NLT) of complexes 7-9 was determined at 532 nm using ns pulses. All three phthalocyanines behave as reverse saturable absorbers with increasing efficiency of optical limiting in the order 7 < 8 < 9. A comparative analysis of the NLT results is attempted in terms of the structural differences in 7-9. © 2010 Elsevier B.V. All rights reserved.
2010
nonlinear optics; phthalocyanines; sulfonamides
01 Pubblicazione su rivista::01a Articolo in rivista
Synthesis and high ranked NLT properties of new sulfonamide-substituted indium phthalocyanines / Efa, Carvalho; Mjf, Calvete; Jose A. S., Cavaleiro; Dini, Danilo; Moreno, Meneghetti; Augusto C., Tome. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 363:14(2010), pp. 3945-3950. [10.1016/j.ica.2010.07.062]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/136035
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