In this work the possibility of using the hydrogen peroxide lifetime as indicator of the oxidation efficiency of Fenton’s and Fenton-like processes for soil treatment was explored. A reactivity scale, in terms of the oxidizing power in the different tested operating conditions (pH, iron sulfate concentration and stabilizer concentration) was built for each soil as a function of the hydrogen peroxide lifetime. Its validity was then confirmed through 3-chlorophenol Fenton’s and Fenton-like slurry-phase oxidation experiments. The proposed reactivity scale proved to be effective for comparing the different operating conditions for the same soil, but failed when used to compare the oxidation performances for different soils, since the different adsorptive behavior of the tested soils may have influenced the contaminant removal rate.

"Hydrogen Peroxide Lifetime as an Indicator of the Efficiency of 3-chlorophenol Fenton's and Fenton-like Oxidation in Soil Slurries" / Baciocchi, R.; Boni, Maria Rosaria; D'Aprile, L.. - In: JOURNAL OF HAZARDOUS MATERIALS. - ISSN 0304-3894. - B96:(2003), pp. 305-329. [10.1016/S0304-3894(02)00218-2]

"Hydrogen Peroxide Lifetime as an Indicator of the Efficiency of 3-chlorophenol Fenton's and Fenton-like Oxidation in Soil Slurries"

BONI, Maria Rosaria;
2003

Abstract

In this work the possibility of using the hydrogen peroxide lifetime as indicator of the oxidation efficiency of Fenton’s and Fenton-like processes for soil treatment was explored. A reactivity scale, in terms of the oxidizing power in the different tested operating conditions (pH, iron sulfate concentration and stabilizer concentration) was built for each soil as a function of the hydrogen peroxide lifetime. Its validity was then confirmed through 3-chlorophenol Fenton’s and Fenton-like slurry-phase oxidation experiments. The proposed reactivity scale proved to be effective for comparing the different operating conditions for the same soil, but failed when used to compare the oxidation performances for different soils, since the different adsorptive behavior of the tested soils may have influenced the contaminant removal rate.
2003
AOPs3-ChlorophenolHydrogen peroxideFentonSoil
01 Pubblicazione su rivista::01a Articolo in rivista
"Hydrogen Peroxide Lifetime as an Indicator of the Efficiency of 3-chlorophenol Fenton's and Fenton-like Oxidation in Soil Slurries" / Baciocchi, R.; Boni, Maria Rosaria; D'Aprile, L.. - In: JOURNAL OF HAZARDOUS MATERIALS. - ISSN 0304-3894. - B96:(2003), pp. 305-329. [10.1016/S0304-3894(02)00218-2]
File allegati a questo prodotto
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/13579
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? 2
  • Scopus 65
  • ???jsp.display-item.citation.isi??? 53
social impact