A review. Modeling the evolution of ion-dipole pairs in a dynamic environment, such as in a solvent cage, requires the knowledge of the intrinsic structural and electronic factors governing their behavior in the unsolvated or microsolvated state. An exptl. methodol. has been developed to this purpose which is based on the generation of tailor-made ionic adducts in gaseous inert media and the investigation of their evolution to products. A survey of the most recent applications of this approach to the gas-phase study of the mechanism and the stereochem. of ionic substitution and addn. reactions is reported.
Microsolvated Ion Stereochemistry / Speranza, Maurizio. - In: JOURNAL OF PHYSICAL ORGANIC CHEMISTRY. - ISSN 0894-3230. - STAMPA. - 15:(2002), pp. 469-469.
Microsolvated Ion Stereochemistry
SPERANZA, Maurizio
2002
Abstract
A review. Modeling the evolution of ion-dipole pairs in a dynamic environment, such as in a solvent cage, requires the knowledge of the intrinsic structural and electronic factors governing their behavior in the unsolvated or microsolvated state. An exptl. methodol. has been developed to this purpose which is based on the generation of tailor-made ionic adducts in gaseous inert media and the investigation of their evolution to products. A survey of the most recent applications of this approach to the gas-phase study of the mechanism and the stereochem. of ionic substitution and addn. reactions is reported.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.