Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazines have been prepared as bis(pyridine) adducts [PY2Fe(XN2)PAPh(6)] (X = S, Se) from the corresponding Mg-II complexes obtained by template co-cyclotetramerization of diphenylfumarodinitrile with 1,2,5-thia/selenadiazolo-3,4-dicarbonitriles, and the unusual direct replacement of Se by S in the reaction of [Py2Fe(SeN2)PAPh(6)] with H2S has been observed.

Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazine: the direct replacement of Se by S in the 1,2,5-selenadiazole ring / Anwar Ul, Haq; Donzello, Maria Pia; Pavel A., Stuzhin. - In: MENDELEEV COMMUNICATIONS. - ISSN 0959-9436. - STAMPA. - 17:6(2007), pp. 337-339. [10.1016/j.mencom.2007.11.013]

Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazine: the direct replacement of Se by S in the 1,2,5-selenadiazole ring

DONZELLO, Maria Pia;
2007

Abstract

Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazines have been prepared as bis(pyridine) adducts [PY2Fe(XN2)PAPh(6)] (X = S, Se) from the corresponding Mg-II complexes obtained by template co-cyclotetramerization of diphenylfumarodinitrile with 1,2,5-thia/selenadiazolo-3,4-dicarbonitriles, and the unusual direct replacement of Se by S in the reaction of [Py2Fe(SeN2)PAPh(6)] with H2S has been observed.
2007
01 Pubblicazione su rivista::01a Articolo in rivista
Iron(II) complexes of hexaphenyl(1,2,5-thia/selenadiazolo)porphyrazine: the direct replacement of Se by S in the 1,2,5-selenadiazole ring / Anwar Ul, Haq; Donzello, Maria Pia; Pavel A., Stuzhin. - In: MENDELEEV COMMUNICATIONS. - ISSN 0959-9436. - STAMPA. - 17:6(2007), pp. 337-339. [10.1016/j.mencom.2007.11.013]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/133370
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