A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by an efficient one-pot mechanosynthesis protocol. The reaction products were characterized by means of complementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction, and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSO solvates are here reported. The described simple and relatively fast (about 1 h for all derivatives) procedure is a good alternative to classical methods performed in organic solvents. © 2019 by the authors

A simple and efficient mechanochemical route for the synthesis of salophen ligands and of the corresponding Zn, Ni, and Pd complexes / Leoni, Luca; Carletta, Andrea; Fusaro, Luca; Dubois, Jean; Tumanov, Nikolay A.; Aprile, Carmela; Wouters, Johan; Dalla Cort, Antonella. - In: MOLECULES. - ISSN 1420-3049. - 24:12(2019). [10.3390/molecules24122314]

A simple and efficient mechanochemical route for the synthesis of salophen ligands and of the corresponding Zn, Ni, and Pd complexes

Leoni, Luca;Dalla Cort, Antonella
2019

Abstract

A number of salophen ligands and their Zn, Ni, and Pd complexes were synthesized by an efficient one-pot mechanosynthesis protocol. The reaction products were characterized by means of complementary solid-state techniques, i.e., powder X-ray diffraction, single-crystal X-ray diffraction, and solid-state NMR spectroscopy. Four new crystal structures of metal salophen complexes as DMSO solvates are here reported. The described simple and relatively fast (about 1 h for all derivatives) procedure is a good alternative to classical methods performed in organic solvents. © 2019 by the authors
2019
salophen ligands; metal salophen complexes; mechanochemistry
01 Pubblicazione su rivista::01a Articolo in rivista
A simple and efficient mechanochemical route for the synthesis of salophen ligands and of the corresponding Zn, Ni, and Pd complexes / Leoni, Luca; Carletta, Andrea; Fusaro, Luca; Dubois, Jean; Tumanov, Nikolay A.; Aprile, Carmela; Wouters, Johan; Dalla Cort, Antonella. - In: MOLECULES. - ISSN 1420-3049. - 24:12(2019). [10.3390/molecules24122314]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1298428
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