Rotational cooling efficiency upon molecular ionization: the case of Li-2(a(3)Sigma(+)(u)) and Li-2(+) (X-2 Sigma(+)(g)) interacting with He-4

The low-temperature (up to about 100 K) collisional (de)excitation cross sections are computed using the full coupled-channel (CC) quantum dynamics for both Li-2 and Li-2(+) molecular targets in collision with He-4. The interaction forces are obtained from fairly accurate ab initio calculations and the corresponding pseudo-rates are also computed. The results show surprising similarities between sizes of inelastic flux distributions within final states in both systems and the findings are connected with the structural change in the molecular rotor features when the neutral species is replaced by its ionic counterpart.