Cold-gas spray (CGS) deposition of amorphous steel coatings starting from a commercial feedstock powder containing boron, tungsten, and silicon was investigated. Microstructural characterization, carried out by X-ray diffraction (XRD), transmission electron microscopy, and backscattered electron diffraction (EBSD) analysis, confirmed the amorphous nature of deposited coatings. The amorphization phenomenon is related to high-strain/strain-rate deformation with shear instability caused by very high particle kinetic energy, with a mechanism that resembles the severe plastic deformation process. The CGS coatings were heat-treated at temperatures ranging from 650 to 850 ◦C to induce partial recrystallization. The effect of nanocrystal nucleation and growth on the hardness of the coatings was investigated, and the hardness of heat-treated samples was found to increase with respect to as-sprayed coatings, outperforming conventional high-velocity oxy-fuel (HVOF) deposits. Hardness was found to decrease after prolonged (<90 min) or higher temperature (>750 ◦C) exposures.

Amorphous steel coatings deposited by cold-gas spraying / Tului, Mario; Bartuli, Cecilia; Bezzon, Alessia; Marino, Angelo Luigi; Marra, Francesco; Matera, Susanna; Pulci, Giovanni. - In: METALS. - ISSN 2075-4701. - 9:6(2019), pp. 1-11. [10.3390/met9060678]

Amorphous steel coatings deposited by cold-gas spraying

Bartuli, Cecilia
;
Marra, Francesco;Pulci, Giovanni
Ultimo
2019

Abstract

Cold-gas spray (CGS) deposition of amorphous steel coatings starting from a commercial feedstock powder containing boron, tungsten, and silicon was investigated. Microstructural characterization, carried out by X-ray diffraction (XRD), transmission electron microscopy, and backscattered electron diffraction (EBSD) analysis, confirmed the amorphous nature of deposited coatings. The amorphization phenomenon is related to high-strain/strain-rate deformation with shear instability caused by very high particle kinetic energy, with a mechanism that resembles the severe plastic deformation process. The CGS coatings were heat-treated at temperatures ranging from 650 to 850 ◦C to induce partial recrystallization. The effect of nanocrystal nucleation and growth on the hardness of the coatings was investigated, and the hardness of heat-treated samples was found to increase with respect to as-sprayed coatings, outperforming conventional high-velocity oxy-fuel (HVOF) deposits. Hardness was found to decrease after prolonged (<90 min) or higher temperature (>750 ◦C) exposures.
2019
amorphous metal; metallic glass; cold spray; XRD; EBSD
01 Pubblicazione su rivista::01a Articolo in rivista
Amorphous steel coatings deposited by cold-gas spraying / Tului, Mario; Bartuli, Cecilia; Bezzon, Alessia; Marino, Angelo Luigi; Marra, Francesco; Matera, Susanna; Pulci, Giovanni. - In: METALS. - ISSN 2075-4701. - 9:6(2019), pp. 1-11. [10.3390/met9060678]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1285790
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