Hot corrosion affects the components of diesel engines and gas turbines working at high temperatures, in the presence of low-melting salts and oxides, such as sodium sulfate and vanadium oxide. Thermal-sprayed coatings of nickel–chromium-based alloys reinforced with ceramic phases, can improve the hot corrosion and erosion resistance of exposed metals, and a sealing thermal, post-treatment can prove effective in reducing the permeability of aggressive species. In this study, the effect of purposely-optimized high-power diode laser reprocessing on the microstructure and type II hot corrosion resistance of cermet coatings of various compositions was investigated. Three different coatings were produced by high velocity oxy-fuel and was tested in the presence of a mixture of Na2SO4 and V2O5 at 700 °C, for up to 200 h: (i) Cr3C2–25% NiCr, (ii) Cr3C2–25% CoNiCrAlY, and (iii) mullite nano–silica–60% NiCr. Results evidenced that laser sealing was not effective in modifying the mechanism, on the basis of the hot corrosion degradation but could provide a substantial increase of the surface hardness and a significant decrease of the overall coating material consumption rate (coating recession), induced by the high temperature corrosive attack.
Hot corrosion resistance of laser-sealed thermal-sprayed cermet coatings / Baiamonte, Lidia; Bartuli, Cecilia; Marra, Francesco; Gisario, Annamaria; Pulci, Giovanni. - In: COATINGS. - ISSN 2079-6412. - 9:6(2019), pp. 347-364. [10.3390/coatings9060347]
Hot corrosion resistance of laser-sealed thermal-sprayed cermet coatings
Baiamonte, Lidia;Bartuli, Cecilia
;Marra, Francesco;Gisario, Annamaria;Pulci, Giovanni
2019
Abstract
Hot corrosion affects the components of diesel engines and gas turbines working at high temperatures, in the presence of low-melting salts and oxides, such as sodium sulfate and vanadium oxide. Thermal-sprayed coatings of nickel–chromium-based alloys reinforced with ceramic phases, can improve the hot corrosion and erosion resistance of exposed metals, and a sealing thermal, post-treatment can prove effective in reducing the permeability of aggressive species. In this study, the effect of purposely-optimized high-power diode laser reprocessing on the microstructure and type II hot corrosion resistance of cermet coatings of various compositions was investigated. Three different coatings were produced by high velocity oxy-fuel and was tested in the presence of a mixture of Na2SO4 and V2O5 at 700 °C, for up to 200 h: (i) Cr3C2–25% NiCr, (ii) Cr3C2–25% CoNiCrAlY, and (iii) mullite nano–silica–60% NiCr. Results evidenced that laser sealing was not effective in modifying the mechanism, on the basis of the hot corrosion degradation but could provide a substantial increase of the surface hardness and a significant decrease of the overall coating material consumption rate (coating recession), induced by the high temperature corrosive attack.File | Dimensione | Formato | |
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