Violation of Distribution Symmetry in Statistical Evaluation of Absolute Enantioselective Synthesis.

Barabas, B.; Caglioti, Luciano; Zucchi, C.; Maioli, M.; Gal, E.; Micskei, K.; Palyi, G.

doi:10.1021/jp072945+

Enantiomeric excesses obtained in absolute enantioselective synthesis by chiral autocatalysis (Soai-reaction) were statistically analyzed. Two sets of parallel experiments, which were performed under chemically different conditions, are available. One group contains 37, while the other contains 84 preparative results. The former group shows some interesting tendencies but does not give conclusive statistical results. The sample of 84 parallel experiments, providing 39 R- and 45 S-excesses have shown that these data represent two distinct, non-symmetric sets with different non-Gaussian distributions. Clear S preference was found.

Violation of Distribution Symmetry in Statistical Evaluation of Absolute Enantioselective Synthesis / B., Barabas; Caglioti, Luciano; C., Zucchi; M., Maioli; E., Gal; K., Micskei; G., Palyi. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - STAMPA. - 111(2007), pp. 11506-11510. [10.1021/jp072945+]

Scheda prodotto non validato

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Titolo:	Violation of Distribution Symmetry in Statistical Evaluation of Absolute Enantioselective Synthesis.
Autori:	B. BARABAS CAGLIOTI, Luciano C. ZUCCHI M. MAIOLI E. GAL K. MICSKEI G. PALYI mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2007
Rivista:	JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL
Citazione:	Violation of Distribution Symmetry in Statistical Evaluation of Absolute Enantioselective Synthesis / B., Barabas; Caglioti, Luciano; C., Zucchi; M., Maioli; E., Gal; K., Micskei; G., Palyi. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - STAMPA. - 111(2007), pp. 11506-11510. [10.1021/jp072945+]
Handle:	http://hdl.handle.net/11573/11981
Appartiene alla tipologia:	01a Articolo in rivista

File allegati a questo prodotto

Non ci sono file associati a questo prodotto.

Utilizza questo identificativo per citare o creare un link a questo documento:
http://hdl.handle.net/11573/11981

Citazioni

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Catalogo dei prodotti della ricerca

Scheda prodotto non validato

File allegati a questo prodotto