A simple empirical formula enables the quantitative description of chiral autocatalysis. This formula was used for the prediction of the number of consecutive autocatalytic reaction cycles needed to obtain a high enantiomeric excess without chiral auxiliary or an asymmetric physical field (absolute enantioselective synthesis). The results show, that even less selective Soai-type systems can be used for absolute enantioselective synthesis, which, therefore, appears to be a fairly general phenomenon. (c) 2006 Published by Elsevier Ltd.

Generalization possibilities of autocatalytic absolute enantioselective synthesis / Karoly, Micskei; Marco, Maioli; Claudia, Zucchi; Caglioti, Luciano; Gyula, Palyi. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 17:21(2006), pp. 2960-2962. [10.1016/j.tetasy.2006.11.016]

Generalization possibilities of autocatalytic absolute enantioselective synthesis

CAGLIOTI, Luciano;
2006

Abstract

A simple empirical formula enables the quantitative description of chiral autocatalysis. This formula was used for the prediction of the number of consecutive autocatalytic reaction cycles needed to obtain a high enantiomeric excess without chiral auxiliary or an asymmetric physical field (absolute enantioselective synthesis). The results show, that even less selective Soai-type systems can be used for absolute enantioselective synthesis, which, therefore, appears to be a fairly general phenomenon. (c) 2006 Published by Elsevier Ltd.
2006
01 Pubblicazione su rivista::01a Articolo in rivista
Generalization possibilities of autocatalytic absolute enantioselective synthesis / Karoly, Micskei; Marco, Maioli; Claudia, Zucchi; Caglioti, Luciano; Gyula, Palyi. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 17:21(2006), pp. 2960-2962. [10.1016/j.tetasy.2006.11.016]
File allegati a questo prodotto
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/11979
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 29
  • ???jsp.display-item.citation.isi??? 28
social impact