The only known example of chiral autocatalysis is the alkylation of N-heterocyclic aldehydes with iPr(2)Zn (Soai reaction). The mechanism and some details of this reaction are not yet clear. An empirical formula is proposed here for the description of this chiral autocatalytic reaction. This formula allows the calculation of some very informative parameters.

Empirical description of chiral autocatalysis / Karoly, Micskei; Gyorgy, Pota; Caglioti, Luciano; Gyula, Palyi. - In: JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY. - ISSN 1089-5639. - STAMPA. - 110:18(2006), pp. 5982-5984. [10.1021/jp0614502]

Empirical description of chiral autocatalysis

CAGLIOTI, Luciano;
2006

Abstract

The only known example of chiral autocatalysis is the alkylation of N-heterocyclic aldehydes with iPr(2)Zn (Soai reaction). The mechanism and some details of this reaction are not yet clear. An empirical formula is proposed here for the description of this chiral autocatalytic reaction. This formula allows the calculation of some very informative parameters.
2006
01 Pubblicazione su rivista::01a Articolo in rivista
Empirical description of chiral autocatalysis / Karoly, Micskei; Gyorgy, Pota; Caglioti, Luciano; Gyula, Palyi. - In: JOURNAL OF PHYSICAL CHEMISTRY. A, MOLECULES, SPECTROSCOPY, KINETICS, ENVIRONMENT, & GENERAL THEORY. - ISSN 1089-5639. - STAMPA. - 110:18(2006), pp. 5982-5984. [10.1021/jp0614502]
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/11920
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