Intermediates of the cobalt carbonyl-catalysed carbonylation of ortho-substituted benzyl halides were identified by IR, View the MathML source- and View the MathML source-NMR spectra. The molecular structures of the acyl-type derivatives 2-MeC6H4CH2C(O)Co(CO)3PPh3 and 2-PhC6H4CH2C(O)Co(CO)3PPh3 were determined by X-ray crystallography. Structural features of these complexes are discussed. Intermediates of the cobalt carbonyl-catalysed carbonylation of ortho-substituted benzyl halides were identified by IR, View the MathML source- and View the MathML source-NMR spectra. The molecular structures of the acyl-type derivatives 2-MeC6H4CH2C(O)Co(CO)3PPh3 and 2-PhC6H4CH2C(O)Co(CO)3PPh3 were determined by X-ray crystallography.
Intermediates of cobalt-catalysed PTC carbonylation of benzyl halides / H., Alper; L., Bencze; R., Boese; Caglioti, Luciano; R., Kurdi; G., Palyi; S., Tiddia; D., Turrini; C., Zucchi. - In: JOURNAL OF MOLECULAR CATALYSIS. A: CHEMICAL. - ISSN 1381-1169. - STAMPA. - 204:(2003), pp. 227-233. [10.1016/s1381-1169(03)00303-0]
Intermediates of cobalt-catalysed PTC carbonylation of benzyl halides
CAGLIOTI, Luciano;
2003
Abstract
Intermediates of the cobalt carbonyl-catalysed carbonylation of ortho-substituted benzyl halides were identified by IR, View the MathML source- and View the MathML source-NMR spectra. The molecular structures of the acyl-type derivatives 2-MeC6H4CH2C(O)Co(CO)3PPh3 and 2-PhC6H4CH2C(O)Co(CO)3PPh3 were determined by X-ray crystallography. Structural features of these complexes are discussed. Intermediates of the cobalt carbonyl-catalysed carbonylation of ortho-substituted benzyl halides were identified by IR, View the MathML source- and View the MathML source-NMR spectra. The molecular structures of the acyl-type derivatives 2-MeC6H4CH2C(O)Co(CO)3PPh3 and 2-PhC6H4CH2C(O)Co(CO)3PPh3 were determined by X-ray crystallography.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
