The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtainedresults highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the VxOy skeleton or a terminal VObond.
Vanadium hydroxide clusters in the gas phase: bond-forming reactions of doubly-charged negative ions by SO2-promoted V-O bond activation / Troiani, Anna; Rosi, Marzio; Garzoli, Stefania; Salvitti, Chiara; DE PETRIS, Giulia. - In: CHEMISTRY-A EUROPEAN JOURNAL. - ISSN 0947-6539. - STAMPA. - 23:49(2017), pp. 11752-11756. [10.1002/chem.201702165]
Vanadium hydroxide clusters in the gas phase: bond-forming reactions of doubly-charged negative ions by SO2-promoted V-O bond activation.
Anna Troiani
Investigation
;ROSI, MARZIOMethodology
;Stefania GarzoliFormal Analysis
;Chiara SalvittiData Curation
;Giulia de Petris
Writing – Review & Editing
2017
Abstract
The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtainedresults highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the VxOy skeleton or a terminal VObond.| File | Dimensione | Formato | |
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