The time evolution of both dynamic and static structure factors of a charged colloidal clay, Laponite, dispersed in both H2O and D2O solvents has been investigated through multiangle dynamic light scattering (DLS) and smallangle X-ray scattering (SAXS) as a function of weight concentration. The aging phenomenology and the formation of arrested states, both gel and glass, are preserved in D2O, while the dynamics is slowed down with respect to water. These findings are important to understand the role played by the solvent in the interparticle interactions and for techniques such as neutron scattering and nuclear magnetic resonance that allow for the extension of the accessible scattering vectors and time scales.
Isotopic effect on the gel and glass formation of a charged colloidal clay: Laponite / Marques, Flavio Augusto De Melo; Angelini, Roberta; Ruocco, Giancarlo; Ruzicka, Barbara. - In: JOURNAL OF PHYSICAL CHEMISTRY. B, CONDENSED MATTER, MATERIALS, SURFACES, INTERFACES & BIOPHYSICAL. - ISSN 1520-6106. - 121:17(2017), pp. 4576-4582. [10.1021/acs.jpcb.6b12596]
Isotopic effect on the gel and glass formation of a charged colloidal clay: Laponite
Marques, Flavio Augusto De Melo;Ruocco, Giancarlo;Ruzicka, Barbara
2017
Abstract
The time evolution of both dynamic and static structure factors of a charged colloidal clay, Laponite, dispersed in both H2O and D2O solvents has been investigated through multiangle dynamic light scattering (DLS) and smallangle X-ray scattering (SAXS) as a function of weight concentration. The aging phenomenology and the formation of arrested states, both gel and glass, are preserved in D2O, while the dynamics is slowed down with respect to water. These findings are important to understand the role played by the solvent in the interparticle interactions and for techniques such as neutron scattering and nuclear magnetic resonance that allow for the extension of the accessible scattering vectors and time scales.File | Dimensione | Formato | |
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