The valence electronic structure of epichlorohydrin, because of its importance as a model chiral system, has been investigated by Angle-Resolved- and Threshold-Photoelectron Spectroscopies (ARPES and TPES) using circular and linear polarized light. The controversial assignments of the valence electronic structure of the molecule impede a full understanding of chiroptical properties such as the circular dichroism exhibited in the valence photoelectron angular distribution of its enantiomers. Addressing this issue by a combined experimental and theoretical investigation is here highlighted.
Scheda prodotto non validato
Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo
Titolo: | The valence electronic structure and conformational flexibility of epichlorohydrine | |
Autori: | ||
Data di pubblicazione: | 2011 | |
Handle: | http://hdl.handle.net/11573/429231 | |
Appartiene alla tipologia: | 03b Edizione Critica |