Inspired by experimental evidence collected when processing thin films from ternary solutions made of two solutes, typically polymers, and one solvent, we computationally study the morphology formation of domains obtained in three-state systems using both a lattice model and a continuum counterpart. The lattice-based approach relies on the Blume–Capel nearest neighbor model with bulk conservative Kawasaki dynamics, whereas as continuum system we consider a coupled system of evolution equations that is derived as hydrodynamic limit when replacing the nearest neighbor interaction in the lattice case by a suitable Kac potential. We explore how the obtained morphology depends on the solvent content in the mixture. In particular, we study how these scenarios change when the solvent is allowed to evaporate.

Pattern formation in three-state systems: towards understanding morphology formation in the presence of evaporation / Cirillo, E. N. M.; Lyons, R.; Muntean, A.; Muntean, S. A.. - (2025), pp. 71-85. - ADVANCED STRUCTURED MATERIALS. [10.1007/978-3-031-84379-2_6].

Pattern formation in three-state systems: towards understanding morphology formation in the presence of evaporation

Cirillo E. N. M.;
2025

Abstract

Inspired by experimental evidence collected when processing thin films from ternary solutions made of two solutes, typically polymers, and one solvent, we computationally study the morphology formation of domains obtained in three-state systems using both a lattice model and a continuum counterpart. The lattice-based approach relies on the Blume–Capel nearest neighbor model with bulk conservative Kawasaki dynamics, whereas as continuum system we consider a coupled system of evolution equations that is derived as hydrodynamic limit when replacing the nearest neighbor interaction in the lattice case by a suitable Kac potential. We explore how the obtained morphology depends on the solvent content in the mixture. In particular, we study how these scenarios change when the solvent is allowed to evaporate.
2025
Advanced Structured Materials
9783031843792
Kawasaki dynamics; lattice models; lattice-based; morphology formation; pattern formation; thin-films; three-state systems
02 Pubblicazione su volume::02a Capitolo o Articolo
Pattern formation in three-state systems: towards understanding morphology formation in the presence of evaporation / Cirillo, E. N. M.; Lyons, R.; Muntean, A.; Muntean, S. A.. - (2025), pp. 71-85. - ADVANCED STRUCTURED MATERIALS. [10.1007/978-3-031-84379-2_6].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11573/1740559
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