The electrochemical generation of chiral enolates is here described, either by cathodic reduction of a C-Br bond or using electrogenerated acetonitrile anion. The reactivity of these enolates have been studied in carboxylation, alkylation and conjugate addiction reactions, obtaining in some cases a good diastereoselectivity.
Electrochemically induced diastereoselective functionalization of N-acyloxazolidin-2-ones / Feroci, Marta; Orsini, M; Palombi, L; Inesi, Achille. - STAMPA. - 2003-12(2003), pp. 29-32.
Electrochemically induced diastereoselective functionalization of N-acyloxazolidin-2-ones
FEROCI, Marta;INESI, ACHILLE
2003
Abstract
The electrochemical generation of chiral enolates is here described, either by cathodic reduction of a C-Br bond or using electrogenerated acetonitrile anion. The reactivity of these enolates have been studied in carboxylation, alkylation and conjugate addiction reactions, obtaining in some cases a good diastereoselectivity.File allegati a questo prodotto
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