Electrochemically reduced polyhaloketones react with amines and phenols aording the corresponding a,bunsaturated amides and esters in moderate yields. The formation of a-iminoketones and a-diimines (main products of the chemical reaction) is completely avoided. The stereochemistry of the a,b-unsaturated products is independent of the nature of the nucleophiles and haloketones.
Electrochemically-induced Favorskii rearrangement / Feroci, Marta; Inesi, Achille; M. RIZZUTO AND L., Rossi. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - (1998), pp. 57-57.
Electrochemically-induced Favorskii rearrangement
FEROCI, Marta;INESI, ACHILLE;
1998
Abstract
Electrochemically reduced polyhaloketones react with amines and phenols aording the corresponding a,bunsaturated amides and esters in moderate yields. The formation of a-iminoketones and a-diimines (main products of the chemical reaction) is completely avoided. The stereochemistry of the a,b-unsaturated products is independent of the nature of the nucleophiles and haloketones.File allegati a questo prodotto
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